Yes, alkyd paint can go over oil paint because alkyd is essentially a modified oil-based paint and the two are chemically compatible. Both oil paint and alkyd paint cure by oxidation and use solvents, so alkyd adheres well to existing oil-based paint when the surface is properly prepared. To do it correctly, you should first clean the surface with soap and water or TSP to remove grease, dirt, and grime, then lightly sand the existing oil paint with 150 to 220 grit sandpaper to degloss the surface and create a mechanical key for adhesion, because glossy oil paint can be too slick for good bonding. After sanding, wipe off all dust with a tack cloth or damp rag. If the existing oil paint is in good condition, well adhered, and not peeling, you can apply alkyd paint directly over it without a primer, though a bonding primer helps if you are making a drastic color change, covering stains, or the surface is very glossy. Alkyd over oil is common for trim, cabinets, doors, and furniture where a hard, durable enamel finish is desired. You cannot apply water-based latex directly over oil without proper sanding and priming, as it may peel, but alkyd over oil works well.
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