Vinegar is highly acidic and will cause immediate, severe damage to natural marble known as chemical etching, which eats away at the calcium carbonate mineral structure. When vinegar contacts a marble surface, it instantly dissolves the polished finish, leaving behind a dull, chalky, rough patch that permanently mars the appearance of the stone. Because marble is acid-sensitive, owners must strictly avoid vinegar, lemon juice, and other acidic substances during cleaning.
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