While distilled white vinegar is a fantastic natural cleaner and fabric softener for standard cotton garments, you should never use vinegar when washing clothes made from natural protein fibers like silk and wool, or garments featuring elastic bands and delicate waterproof technical gear. The mild acetic acid in vinegar can weaken delicate silk protein threads, degrade natural wool fibers, and break down the stretch elasticity of spandex and rubberized waistbands over time. You can troubleshoot fabric safety easily by checking garment care tags. You can verify that you are protecting your wardrobe when washing delicate woolens and silks with neutral detergents while reserving vinegar solely for heavy cottons, towels, and synthetic athletic wear.
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